Selective monoalkylation of p-tert-butylcalix-[4]-arene in a methyl carbonate ionic liquid
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چکیده
منابع مشابه
Selective Oxidation of 25,27-Bis- (3-formylphenoxylethoxy)-p-tert-butylcalix[4]arene
Reaction of 25,27-bis-(3-formylphenoxyethoxy)-p-tert-butylcalix[4]arene (1) with 20% mole of KCN in ethanol and i-propanol yielded monoethylester (2) (50%) and monoisopropylester (3) (15%). Compound 1 was not oxidized by air in the absence of KCN under reflux. The Cannizzaro reaction of 1 in ethanol using KOH gave bis-alcohol (4), acid-alcohol (5).
متن کاملElectrochemical Investigation of P-Tert-Butylcalix[6]Arene Modified Gold Electrode for Ionic Detection
The aim of this work was to study the electrochemical behavior of gold electrode which was modified with p-tert-butylcalix[6]arene membrane and this in the presence of different nickel ions based concentrations in order to form a nickel electrochemical sensor. For that, impedance-spectroscopy characteristics have been investigated. The obtained results were then modeled by appropriate equivalen...
متن کاملCationic recognition by tert-butylcalix[4]arene-functionalized nanoprobes.
A nanoparticle-based strategy has been demonstrated using structurally-tailored tert-butylcalixarenes immobilized on gold nanoparticles to tune the guest access to the calixarene cone cavity for cationic recognition. This strategy exploits the interparticle charge-induced aggregation upon selective capture of metal cations into the nanoparticle-immobilized tert-butylcalixarenes, which produces ...
متن کاملSynthesis of Novel p-tert-Butylcalix[4]arene Derivative: Structural Characterization of a Methanol Inclusion Compound
A p-tertbutylcalix[4]arene derivative was synthesized from a reaction of the diisothiocyanate p-tertbutylcalix[4]arene, obtaining crystals that were then characterized by mass spectroscopy, Raman spectroscopy, and single-crystal X-ray diffraction. The molecule presents two acid carbamothioic-n-ethoxy-methyl-ester substituent groups. Through crystallization of this compound, it was also found th...
متن کاملComparative study of tributyltin adsorption onto mesoporous silica functionalized with calix[4]arene, p-tert-butylcalix[4]arene and p-sulfonatocalix[4]arene.
The adsorption of tributyltin (TBT), onto three mesoporous silica adsorbents functionalized with calix[4]arene, p-tert-butylcalix[4]arene and p-sulfonatocalix[4]arene (MCM-TDI-C4, MCM-TDI-PC4 and MCM-TDI-C4S, respectively) has been compared. Batch adsorption experiments were carried out and the effect of contact time, initial TBT concentration, pH and temperature were studied. The Koble-Corriga...
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2018
ISSN: 1359-7345,1364-548X
DOI: 10.1039/c8cc05566a